Permanently Ungroup Certain Programs

It would be nice to be able to specify certain programs to always be ungrouped, while letting the other programs stay grouped. An example would running Citrix apps. Windows groups all of the Citrix apps into a group even though the Citrix apps are streaming different server apps. So, it would be nice to be able to tell you program to always ungroup the Citrix Receiver ... for instance. Or maybe you would want chat applications to always be ungrouped for easy access to each chat window.